20.109(F11): Mod 3 Day 4 Solar cell assembly: Difference between revisions
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==Introduction== | ==Introduction== | ||
[[Image:Screen shot 2011-11-16 at 11.02.56 PM.png|thumb|x300px]] | [[Image:Screen shot 2011-11-16 at 11.02.56 PM.png|thumb|x300px]] | ||
The principle of our dye-sensitized solar cells is that light absorption by a dye will provide the energy to transfer its electrons to a mixture of Titania and Titania coated SWNT:phage complexes, which will act as a shuttle to deliver the electrons to an external circuit for extraction of "useful" energy. To complete the cell an Iodide redox mediator is used to recycle electrons back to the dye from a counter-electrode. During the first two lab sessions of this third module, you worked to coat genetically-modified M13 phage with | The principle of our dye-sensitized solar cells is that light absorption by a dye will provide the energy necessary to transfer its electrons to a mixture of Titania and Titania coated single walled carbon nano-tube(SWNT):phage complexes, which will act as a shuttle to deliver the electrons to an external circuit for extraction of "useful" energy. To complete the cell an Iodide redox mediator is used to recycle electrons back to the dye from a counter-electrode. During the first two lab sessions of this third module, you worked to coat genetically-modified M13 phage with SWNTs and to mineralize TiO<sub>2</sub> upon them. (These steps are summarized visually in the top of the figure to the right) For today's session, you will use these complexes to construct the anode of the dye-sensitized solar cell. (The anode can be seen in the bottom left of the image to the right) | ||
Revision as of 16:55, 17 November 2011
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Solar Cell Assembly
Introduction
The principle of our dye-sensitized solar cells is that light absorption by a dye will provide the energy necessary to transfer its electrons to a mixture of Titania and Titania coated single walled carbon nano-tube(SWNT):phage complexes, which will act as a shuttle to deliver the electrons to an external circuit for extraction of "useful" energy. To complete the cell an Iodide redox mediator is used to recycle electrons back to the dye from a counter-electrode. During the first two lab sessions of this third module, you worked to coat genetically-modified M13 phage with SWNTs and to mineralize TiO2 upon them. (These steps are summarized visually in the top of the figure to the right) For today's session, you will use these complexes to construct the anode of the dye-sensitized solar cell. (The anode can be seen in the bottom left of the image to the right)
Protocols
While You Were Out
The TiO2 mineralized SWNT:phage complexes that you left last time were dried in a vacuum oven at room temperature. The dried substance was then ground, using a mortar and pestle, into a powder on the micrometer scale. To this ground material, a paste of pure TiO2, ethyl cellulose (for viscosity) and terpineol (an organic solvent) was added. To the right can be seen the image of the paste before the SWNT:Titania powder was added (left) and after (right).
The base of the anode has also been prepared. It consists of a piece of glass coated on one side with 2mm of Florine-doped Tin Oxide (FTO). Doping is the controlled introduction of impurities into a substance for the purpose of adjusting a chemical property of interest. In this case, the Tin Oxide has been doped with Florine for the purpose of increasing its conductance.
