Crystallization of metal complexes: Difference between revisions
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Matthew Todd (talk | contribs) (New page: Typical add-ins are PF6-, BF4-, Ph4B-, Cl4Zn2-. Usually use MeOH or MeCN as solvents for these. Typical mixed-solvent diffusion tank methods are to dissolve the sample in MeCN, acetone, D...) |
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Typical add-ins are PF6-, BF4-, Ph4B-, Cl4Zn2-. Usually use MeOH or MeCN as solvents for these. | Typical add-ins are PF6-, BF4-, Ph4B-, Cl4Zn2-. Usually use MeOH or MeCN as solvents for these. | ||
Typical mixed-solvent diffusion tank methods are to dissolve the sample in MeCN, acetone, DMF or MeOH and allow ether to diffuse in. | Typical mixed-solvent diffusion tank methods are to dissolve the sample in MeCN, acetone, DMF or MeOH and allow ether to diffuse in. | ||
Typical metals (generally) for cyclam recrysts are Cd, Ag (dark), Hg or Pb (usually sit on azamacrocycle, rather than in it). Fe(II)(BF4-)2 in MeCN is good. | Typical metals (generally) for cyclam recrysts are Cd, Ag (dark), Hg or Pb (usually sit on azamacrocycle, rather than in it). Fe(II)(BF4-)2 in MeCN is good. | ||
Latest revision as of 03:44, 9 September 2010
Typical add-ins are PF6-, BF4-, Ph4B-, Cl4Zn2-. Usually use MeOH or MeCN as solvents for these. Typical mixed-solvent diffusion tank methods are to dissolve the sample in MeCN, acetone, DMF or MeOH and allow ether to diffuse in. Typical metals (generally) for cyclam recrysts are Cd, Ag (dark), Hg or Pb (usually sit on azamacrocycle, rather than in it). Fe(II)(BF4-)2 in MeCN is good.
