User:Abigail E. Miller/Notebook/MOF Project/2013/01/23

Objective

• exchange DPNI for adenine in PPF-18 (PPF-18A)
• powder XRD of PPF-18A
• filter, collect and powder XRD of attempt to synthesis MOF with DO2A

Bench Work

• 9am removed DO2A plus zinc reaction from the solution
  • yellowish solution with white suspension
  • white solid material on bottom and sides of vial
  • let cool to room temp on the bench t

• also removed PPF18 and PPF18A samples from powder XRD
  • sensor, went off due to over heating of the X ray source

• exchanging DPNI for adenine
  • mixed 0.5 mL of ethanol and 1.5 mL DEF
  • added 0.0070 mg adenine, but it did not all dissolve
  • collected UVVis spectrum of solution

• Weight of PPF18
  • paper 0.1332 g
  • paper plus PPF18 0.1528 g
  • after putting in 10mL beaker, paper 0.1332 g
  • Some loss of material to static

• 10:20am added 1mL of adenine solution to PPF18
  • waiting 3 hrs

• filtered material from DO2A and zinc reaction

• 1:30 pm filtered PPF18 with adenine
  • filtrate was purple - indicates presence of porphyrin, dissolved from the PPf18
  • washed with DEF

Data/Spectra

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Notes

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