User:Eleni N. Kalivas/Notebook/CHEM-571/2014/08/29: Difference between revisions

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|style="background-color: #EEE"|[[Image:owwnotebook_icon.png|128px]]<span style="font-size:22px;"> Project name</span>
|style="background-color: #EEE"|[[Image:owwnotebook_icon.png|128px]]<span style="font-size:22px;"> Project name</span>
|style="background-color: #F2F2F2" align="center"|<html><img src="/images/9/94/Report.png" border="0" /></html> [[{{#sub:{{FULLPAGENAME}}|0|-11}}|Main project page]]<br />{{#if:{{#lnpreventry:{{FULLPAGENAME}}}}|<html><img src="/images/c/c3/Resultset_previous.png" border="0" /></html>[[{{#lnpreventry:{{FULLPAGENAME}}}}{{!}}Previous entry]]<html>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;</html>}}{{#if:{{#lnnextentry:{{FULLPAGENAME}}}}|[[{{#lnnextentry:{{FULLPAGENAME}}}}{{!}}Next entry]]<html><img src="/images/5/5c/Resultset_next.png" border="0" /></html>}}
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==Solution Preparation==
==Solution Preparation==
*Complete film synthesis
====Complete film synthesis====
# 0.2M Sodium Sulfate Solution
# 0.2M Sodium Sulfate Solution
## I dissolved 22.034g of anhydrous Na<sub>2</sub>SO<sub>4</sub> in 1000mL of water
## I dissolved 22.034g of anhydrous Na<sub>2</sub>SO<sub>4</sub> in 1000mL of water
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## I dissolved 17.042g of NaHCO<sub>3</sub> in 1000mL of water
## I dissolved 17.042g of NaHCO<sub>3</sub> in 1000mL of water
## This solution will be used to neutralize the acid in your films
## This solution will be used to neutralize the acid in your films
====Malachite Green Solutions====
*200ppm, Calculations can be seen on [[User:James C. Schwabacher/Notebook/CHEM-571/2014/08/29|James Schwabacher's]] Notebook
*80ppm, Calculations can be seen on [[User:James C. Schwabacher/Notebook/CHEM-571/2014/08/29|James Schwabacher's]] Notebook
*8ppm, Calculations can be seen on [[User:James C. Schwabacher/Notebook/CHEM-571/2014/08/29|James Schwabacher's]] Notebook
*2ppm, Calculations can be seen [[User:Madeleine Y. Bee/Notebook/CHEM-581 Experimental Chemistry/2014/08/29|Madeline Bee's]] notebook
*1.7ppm, Calculations can be seen [[User:Madeleine Y. Bee/Notebook/CHEM-581 Experimental Chemistry/2014/08/29|Madeline Bee's]] notebook
*1.4ppm,  437.5uL of the 8ppm was made in a total of 25mL volumetric
*1.1ppm, 19.643mL of the 1.4ppm was made in a total of 25mL volumetric
*0.5ppm, Calculations can be seen on [[User:Michael S. Bible/Notebook/581/2014/08/29|Michael Bible's]] Notebook
*0.2ppm, Calculations can be seen on [[User:Michael S. Bible/Notebook/581/2014/08/29|Michael Bible's]] Notebook


*New film synthesis of 10% and 5% clay by weight
==Weight of film soaked in solution==
# Polymer-Clay Films
*Table of PVA films
## Add 7mL of water to 1g of polyvinyl alcohol and 0.05g of sodium montmorillonite in a glass vial
{| {{table}}
## Stir the solution with constant heating at 75C until the polymer is dissolved and the clay is dispersed (~15 minutes)
| align="center" style="background:#f0f0f0;"|'''Concentration'''
## Cool the solution to room temperature
| align="center" style="background:#f0f0f0;"|'''Mass of Vile (g)'''
## Add 0.5mL 0.8 wt% glutaraldehyde.  
| align="center" style="background:#f0f0f0;"|'''Mass of Vile w/ PVA (g)'''
## Stir for an additional 3 minutes to ensure homogeneity
| align="center" style="background:#f0f0f0;"|'''Mass of PVA (g)'''
## Pour solution into a teflon dish to dry
|-
 
| 2 ppm||13.0988||13.2181||0.1193
*Malachite green solutions
|-
 
| 8 ppm||12.976||13.0168||0.0408
 
|-
 
| 80 ppm||12.8776||13.0108||0.1332
 
|-
==Data==
| 200 ppm||13.0313||13.0879||0.0566
UV-vis spectra of Malachite Green Solutions from 0.2ppm to 8ppm
|}
* Table of PVA-clay films
{| {{table}}
| align="center" style="background:#f0f0f0;"|'''Concentration'''
| align="center" style="background:#f0f0f0;"|'''Mass of Vile (g)'''
| align="center" style="background:#f0f0f0;"|'''Mass of Vile w/ PVA & Clay (g)'''
| align="center" style="background:#f0f0f0;"|'''Mass of PVA & clay (g)'''
|-
| 2 ppm||12.9924||13.0936||0.1012
|-
| 8 ppm||13.1447||13.1854||0.0407
|-
| 80 ppm||13.0441||13.1484||0.1043
|-
| 200 ppm||13.1563||13.2333||0.077
|-
|
|}
   
   


Latest revision as of 00:13, 27 September 2017

Project name Main project page
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Objective

  1. Complete the film synthesis from Wednesday
  2. Start new film synthesis of both polymer films and polymer-clay films.
  3. Make all Malachite green solutions

Protocol

  • Complete Film synthesis from Wednesday August, 27th
  1. Warm 150mL of Sodium Sulfate Solution at 80C for 15 minutes
  2. Place film in Sodium Sulfate Solution at 80C for 1 hour with gentle stirring
  3. Warm 150mL of 1% HCl at 80C for 15 minutes
  4. Place film in 1% HCl Solution (see below for details) at 80C for 30 minutes with gentle stirring
  5. Place film in Sodium Bicarbonate Solution for 15 minutes at room temperature with gentle stirring
  • Starting new film Synthesis

follow the same procedure as Wednesday August 27th

  • Malachite Green Solutions
  1. 25mL 0.20ppm Malachite Green
  2. 25mL 0.50ppm Malachite Green
  3. 25mL 1.1ppm Malachite Green
  4. 25mL 1.4ppm Malachite Green
  5. 25mL 1.7ppm Malachite Green
  6. 50mL 2.0ppm Malachite Green
  7. 50mL 8.0ppm Malachite Green
  8. 50mL 80.0ppm Malachite Green
  9. 50mL 200.0ppm Malachite Green

Solution Preparation

Complete film synthesis

  1. 0.2M Sodium Sulfate Solution
    1. I dissolved 22.034g of anhydrous Na2SO4 in 1000mL of water
    2. I added 100mL of concentrated H2SO4 to this solution
    3. This solution will be used to enable the reaction between polyvinyl alcohol and glutaraldehyde in order to cross link the polymer film
  2. 1% wt. HCl Solution
    1. I added 10mL of concentrated HCl to 985mL of water
    2. This solution will be used to enable the reaction between polyvinyl alcohol and glutaraldehyde in order to cross link the polymer film
  3. 0.2M Sodium Bicarbonate Solution
    1. I dissolved 17.042g of NaHCO3 in 1000mL of water
    2. This solution will be used to neutralize the acid in your films

Malachite Green Solutions

Weight of film soaked in solution

  • Table of PVA films
Concentration Mass of Vile (g) Mass of Vile w/ PVA (g) Mass of PVA (g)
2 ppm 13.0988 13.2181 0.1193
8 ppm 12.976 13.0168 0.0408
80 ppm 12.8776 13.0108 0.1332
200 ppm 13.0313 13.0879 0.0566
  • Table of PVA-clay films
Concentration Mass of Vile (g) Mass of Vile w/ PVA & Clay (g) Mass of PVA & clay (g)
2 ppm 12.9924 13.0936 0.1012
8 ppm 13.1447 13.1854 0.0407
80 ppm 13.0441 13.1484 0.1043
200 ppm 13.1563 13.2333 0.077



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