PPF 18 & PPF 20
- 1.) Add solids 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089 g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol)to small capped vial
- 2.) Add 1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL)
- 3.) Sealed and Sonicated to ensure homogeneity
- 4.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)
- 5.) Add solids to a second vial 5,10,15,20- Tetrakis(4-carboxyl)-21H,23H-porphine (TCPP) (.0079 g, .01 mmol),Zinc nitrate hexahydrate (.0089 g, .03 mmol, N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0168 g, .01 mmol)to small capped vial
- 6.) Add 1.0 M nitric acid (30 μL, .05 mmol) in ethanol, N,N-dimethyl formamide (DMF)(1.5 mL),Ethanol (0.5 mL)
- 7.) Sealed and Sonicated to ensure homogeneity
- 8.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2)
__________________________________________________________________________________________________________________________________________
07/22/13
__________________________________________________________________________________________________________________________________________
07/24/13
- 9.)Took Powder X-ray Diffraction (See Images Below)
|
MOF: Ellen
