User:Ellen Petersen/Notebook/MOF/2013/08/08: Difference between revisions
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|style="background-color: #EEE"|[[Image:owwnotebook_icon.png|128px]]<span style="font-size:22px;"> | |style="background-color: #EEE"|[[Image:owwnotebook_icon.png|128px]]<span style="font-size:22px;"> MOF:Ellen</span> | ||
|style="background-color: #F2F2F2" align="center"| | |style="background-color: #F2F2F2" align="center"|[[File:Report.png|frameless|link={{#sub:{{FULLPAGENAME}}|0|-11}}]][[{{#sub:{{FULLPAGENAME}}|0|-11}}|Main project page]]<br />{{#if:{{#lnpreventry:{{FULLPAGENAME}}}}|[[File:Resultset_previous.png|frameless|link={{#lnpreventry:{{FULLPAGENAME}}}}]][[{{#lnpreventry:{{FULLPAGENAME}}}}{{!}}Previous entry]] }}{{#if:{{#lnnextentry:{{FULLPAGENAME}}}}|[[{{#lnnextentry:{{FULLPAGENAME}}}}{{!}}Next entry]][[File:Resultset_next.png|frameless|link={{#lnnextentry:{{FULLPAGENAME}}}}]]}} | ||
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== | ==PPF-18 w/ various metals== | ||
* | *1.) Add Zinc nitrate hexahydrate (.0072796 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Iron Chloride Porphyrin Mix to a small capped vial labeled PPF-18 w/ Iron Chloride | ||
*2.) Add Zinc nitrate hexahydrate (.002488 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Cobalt Acetate Porphyrin Mix to a small capped vial labeled PPF-18 w/ Cobalt Acetate | |||
*3.) Add Zinc nitrate hexahydrate (.006412 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Cupric Acetate Porphyrin Mix to a small capped vial labeled PPF-18 w/ Cupric Acetate | |||
*4.) Add Zinc nitrate hexahydrate (.0068095 g, .03 mmol), N,N’-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNI) (.0042 g, .01 mmol),1.0 M nitric acid (50 μL, .05 mmol) in ethanol, N,N-diethyl formamide (DEF)(1.5 mL),Ethanol (0.5 mL), & 100μl Nickel Nitrate Porphyrin Mix to a small capped vial labeled PPF-18 w/ Nickel Nitrate | |||
*5.) All vials are sealed and sonicated to ensure homogeneity | |||
*6.) Heated to 80° C in an oven for 24 hours followed by a slow cooling to room temperature for 9 hours (Program 2) | |||
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08--2013 | |||
* 9.) Vacuum Filtration | |||
*10.) Powder X-Ray Diffraction (see images below) | |||
Latest revision as of 23:10, 26 September 2017
MOF:Ellen | Main project page Previous entry |
PPF-18 w/ various metals
_____________________________________________________________________________________________________________________________________________ 08--2013
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