User:Etienne Robillard/Notebook/Formulas

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=== References ===
=== References ===
-
#Wikipedia http://en.wikipedia.org/wiki/Isonitrile
+
<biblio>
#Hoffman1 pmid=16953613
#Hoffman1 pmid=16953613
#Hoffman2 http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch17/ch17-3-4-2.html
#Hoffman2 http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch17/ch17-3-4-2.html
#Hoffman3 http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm
#Hoffman3 http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm
 +
#Wikipedia http://en.wikipedia.org/wiki/Isonitrile
 +
</biblio>

Revision as of 11:40, 6 May 2013

Ugi route to Wilmslow

  1. Step 1: Protonation of the isocyanide carbonyl (C=O) to yield a nucleophilic Schiff base via Hoffman/Ugi reaction: O+2ROH = -RN

References

  1. Pirrung MC and Ghorai S. . pmid:16953613. PubMed HubMed [Hoffman1]
  2. http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch17/ch17-3-4-2.html [Hoffman2]
  3. http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm [Hoffman3]
  4. http://en.wikipedia.org/wiki/Isonitrile [Wikipedia]
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