User:Etienne Robillard/Notebook/Formulas

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Ugi route to Wilmslow

  1. Step 1: Protonation of the isocyanide carbonyl (C=O) to yield a nucleophilic Schiff base via Hoffman/Ugi reaction: O+2ROH = -RN

References

  1. Wikipedia http://en.wikipedia.org/wiki/Isonitrile
  2. Hoffman1 pmid=16953613
  3. Hoffman2 http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch17/ch17-3-4-2.html
  4. Hoffman3 http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm
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