User:James C. Schwabacher/Notebook/CHEM-571/2014/09/19: Difference between revisions
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|style="background-color: #EEE"|[[Image:BDLlogo_notext_lr.png|128px]]<span style="font-size:22px;"> Biomaterials Design Lab</span> | |style="background-color: #EEE"|[[Image:BDLlogo_notext_lr.png|128px]]<span style="font-size:22px;"> Biomaterials Design Lab</span> | ||
|style="background-color: #F2F2F2" align="center"| | |style="background-color: #F2F2F2" align="center"|[[File:Report.png|frameless|link={{#sub:{{FULLPAGENAME}}|0|-11}}]][[{{#sub:{{FULLPAGENAME}}|0|-11}}|Main project page]]<br />{{#if:{{#lnpreventry:{{FULLPAGENAME}}}}|[[File:Resultset_previous.png|frameless|link={{#lnpreventry:{{FULLPAGENAME}}}}]][[{{#lnpreventry:{{FULLPAGENAME}}}}{{!}}Previous entry]] }}{{#if:{{#lnnextentry:{{FULLPAGENAME}}}}|[[{{#lnnextentry:{{FULLPAGENAME}}}}{{!}}Next entry]][[File:Resultset_next.png|frameless|link={{#lnnextentry:{{FULLPAGENAME}}}}]]}} | ||
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==Objective== | ==Objective== | ||
# Finish analyzing PVA-malachite green data | |||
# Retrieve pXRD data | |||
# Start making new PVA and PVA clay films | |||
# Set up experiments (like the malachite green experiments) to see how well the films absorb arsenic and mercury | |||
## Notes: both of these are toxic metals, and we need to understand how to use/work with them. | |||
### Information sheet on [http://www.hse.gov.uk/pubns/indg441.pdf As] | |||
### Information sheet on [http://www.safety.gatech.edu/chemical/mercury_and_compounds.pdf Hg] | |||
==Description== | ==Description== | ||
# | # Finishing the analysis of the PVA-Malachite green data, our data is being compiled into a spread sheet with other groups | ||
# Learning how to extract and interpret the data from the pXRD. Data will be uploaded next week after analysis. | |||
# New PVA and PVA clay films were started | |||
## The procedure for the film synthesis may be viewed [[User:Jacob_Esenther/Notebook/581/2014/08/27|here]]. | |||
### The initial teflon dish containing the PVA film was contaminated with malachite green. The film was tinted blue so the synthesis was repeated. | |||
# Set up for arsenic and mercury absorbance experiment | |||
## Vials were labeled and weighed out with no lid | |||
## Films were cut using a falcon tube and spatula | |||
### Note: The PVA only film seems to soften the longer it soaks in water. | |||
## Vials were weighed again with films present. | |||
## Dilutions of 50ppm, 100ppm and 150ppm of Arsenic and Mercury were created. | |||
==Data== | ==Data== | ||
* | *Mercury stock solution | ||
# 0.0908g HgCl2 | |||
## (0.0908g HgCl2)*(1mol HgCl2/271.5g HgCl2)*(1mol HgCl2/1mol Hg)*(200.59g Hg/1mol Hg) = 0.0671g Hg | |||
## put in 250mL volumetric | |||
## 268ppm Hg | |||
*New Film Synthesis | |||
** PVA Film | |||
*** 1.0005g PVA | |||
**PVA-Clay Film | |||
*** 1.0117g PVA + 0.1105g Clay | |||
*Arsenite solutions for vials from 0.0499 mol/L (3738.588 ppm As) stock. These were made by me and Eleni for the entire class. | |||
# 4 mL of stock in 100 mL volumetric flask -> 150 ppm As | |||
# 2.67 mL of stock in 100 mL volumetric flask -> 100 ppm As | |||
# 1.337 mL of stock in 100 mL volumteric flask -> 50 ppm As | |||
*Mercury solutions for vials from 268 ppm Hg stock. These were prepared by me and Madeleine, to split between our groups. | |||
# 27.985 mL of stock in 50 mL volumetric flask -> 150 ppm | |||
# 18.657 mL of stock in 50 mL volumetric flask -> 100 ppm | |||
# 9.328 mL of stock in 50 mL volumteric flask -> 50 ppm | |||
<u>As and Hg Absorption Experiment Set Up</u> | |||
{| {{table}} | |||
| align="center" style="background:#f0f0f0;"|'''''' | |||
| align="center" style="background:#f0f0f0;"|'''As/Hg''' | |||
| align="center" style="background:#f0f0f0;"|'''Conc. (ppm)''' | |||
| align="center" style="background:#f0f0f0;"|'''Vial (g)''' | |||
| align="center" style="background:#f0f0f0;"|'''Vial+Film (g)''' | |||
| align="center" style="background:#f0f0f0;"|'''Film (g)''' | |||
|- | |||
| |||||||||| | |||
|- | |||
| PVA Only||As ||50||13.11987||13.24774||0.12787 | |||
|- | |||
| ||As||100||13.18897||13.27703||0.08806 | |||
|- | |||
| ||As||150||13.12007||13.17871||0.05864 | |||
|- | |||
| ||Hg||50||13.16106||13.29947||0.13841 | |||
|- | |||
| ||Hg||100||13.17089||13.27604||0.10515 | |||
|- | |||
| ||Hg||150||13.12344||13.28383||0.16039 | |||
|- | |||
| |||||||||| | |||
|- | |||
| PVA-Clay||As ||50||13.08592||13.27636||0.19044 | |||
|- | |||
| ||As||100||13.07435||13.16925||0.0949 | |||
|- | |||
| ||As||150||13.09743||13.23957||0.14214 | |||
|- | |||
| ||Hg||50||13.13946||13.23529||0.09583 | |||
|- | |||
| ||Hg||100||13.11072||13.22965||0.11893 | |||
|- | |||
| ||Hg||150||13.03134||13.14071||0.10937 | |||
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|} | |||
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Latest revision as of 00:19, 27 September 2017
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Objective
Description
Data
As and Hg Absorption Experiment Set Up
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