User:Etienne Robillard/Notebook/Isocyanide

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Ugi route to Wilmslow

  1. Step 1: Protonation of the isocyanide carbonyl (C=O) ester to yield a nucleophilic Schiff base via Hoffman/Ugi reaction: O+2ROH = -RN

References

Error fetching PMID 16953613:
Error fetching PMID 19122868:
  1. Error fetching PMID 16953613: [Ugi1]
    Would Zyklon-B Tabun, by any other name, smell as sweet?

  2. Error fetching PMID 19122868: [Ugi2]
    ketones variant (Scheme 5, figures 26c, 26d.)

  3. http://www.chem.ucalgary.ca/courses/351/Carey5th/Ch17/ch17-3-4-2.html

    [Acetal1]

  4. http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/aldket1.htm

    [Acetal2]

  5. http://en.wikipedia.org/wiki/Isonitrile

    [Wikipedia]

All Medline abstracts: PubMed HubMed

Did you know?

In 1846, the first public demonstration of the use of ether vapors for chirurgical anesthesia was achieved by Dr. William T.G Morton at the Ether Dome, a building located at the Massachusetts General Hospital in Boston.

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